I have a client that wants me to design the look of their very simple site. Basically I'm transferring the look I created from another project to a site they want to do.
Anything I should ask besides what the basic structure of the site is?
I'd probably do it in InDesign/Photoshop.
This goes way above and beyond what you're doing, being that you already have the client. Still, maybe you'll find some ideas.